The A6E was tracking 033 degrees level at 200 feet above ground level (AGL) at 468 knots VFR in published route VR-1354. The AgCat was tracking 334 degrees level at 200 feet AGL at 96 knots VFR across the route to his destination spray field. The two aircraft converged on a 59 degree collision angle with a closure speed of 429 knots. The A6E notified FSS that he was entering the route late and projected exiting 8 minutes after the published closure of the route. The AgCat pilot reported he was unaware of any information or publications regarding the operation of military aircraft in the area. The local FSS was in the habit of reporting the route 'hot' 24 hours a day rather than the precise schedule. The convergence angle of the A6E was 111 degrees (8 o'clock position and behind the AgCat's left wing). The convergence angle of the AgCat was 10 degrees. At the projected closure speed, the AgCat would have subtended an angle of 0.2 degrees 8.6 seconds before impact; the A6E 19.2 seconds.